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</div>  <div class="e_box e_box-000 p_TimeBox "> <div class="e_title e_AssistInfo-001 p_time"> <div class="font"><i class="iconfont"></i> 2019/08/06 13:36 </div> </div> </div> </div> <div class="e_box e_box-000 p_InteractionInfo">  <div class="e_box e_box-000 p_ViewBox"> <div class="e_title e_AssistName-001 p_AssistNameE"> <div class="font"><i class="iconfont"></i><span class="i_browsingVolume">瀏覽量</span></div> </div> <div class="e_title e_AssistInfo-001 p_view" infoDetailId="46"> <div class="font"><i class="iconfont"></i></div> </div> </div>  <div class="e_box e_box-000 p_CommentBox "> <div class="e_title e_AssistName-001 p_AssistNameF "> <div class="font"><i class="iconfont"></i><span class="i_CommentBox">評論：</span></div> </div> <a class="e_link e_link-000 p_LinkA" href="javascript:void(0);" > <div class="e_title e_link-001 p_comment" infoDetailId="46"> <div class="font"><i class="iconfont"></i></div> </div> </a> </div>    </div> </div>  <div class="e_line e_ArticleHline-001 p_ArticleHline"></div>    <div class="e_box e_box-000 p_content ">   <article class="e_HtmlEditor e_HtmlEditor-001 p_articles"> <div class="resetHtmlCssStyle"> <div class="reset_style js-reset_style js-adapMobile "> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">BLUER-PRO硫磺回收技術是煙臺新瑞環?？萍加邢薰咀灾鏖_發的液相氧化催化技術。采用螯合鐵離子作為催化劑，在水溶液中發生如下總反應：</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">H</span><span style="font-size: 13.3333px;">2</span>S + 1/2 O2 → H2O + S°</span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">該反應可分為兩部分：吸收過程和再生過程。</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">吸收部分：</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">配比溶液吸收H</span><span style="font-size: 13.3333px;">2</span>S氣體：</span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">H</span><span style="font-size: 13.3333px;">2</span>S (g) + H2O ↔ H2S (l) + H2O </span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">電離：</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">H</span><span style="font-size: 13.3333px;">2</span>S (l) ↔ H<sup style="font-size: 16px;"><span style="vertical-align:super;">+ </span></sup>+ HS<sup style="font-size: 16px;"><span style="vertical-align:super;">-</span></sup></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">高價鐵離子(Fe+3)氧化二價硫：</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">HS<sup><span style="vertical-align:super;">- </span></sup>+ 2Fe<sup><span style="vertical-align:super;">+3</span></sup> → 2Fe<sup><span style="vertical-align:super;">+2</span></sup> + H<sup><span style="vertical-align:super;">+</span></sup> + S<sup><span style="vertical-align:super;">0</span></sup> </span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">吸收部分總方程式</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">H</span><span style="font-size: 13.3333px;">2</span>S (l) + 2Fe<sup style="font-size: 16px;"><span style="vertical-align:super;">+3</span></sup> → 2H<sup style="font-size: 16px;"><span style="vertical-align:super;">+</span></sup> + S°+ 2Fe<sup style="font-size: 16px;"><span style="vertical-align:super;">+2</span></sup></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">再生部分:</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">配比溶液吸收氧氣：</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">1/2 O<sub><span style="vertical-align:sub;">2</span></sub> (g) + H<sub><span style="vertical-align:sub;">2</span></sub>O ↔ 1/2 O<sub><span style="vertical-align:sub;">2</span></sub> (l) + H<sub><span style="vertical-align:sub;">2</span></sub>O</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">亞鐵離子再生反應 (Fe<sup><span style="vertical-align:super;">+2</span></sup>)</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">1/2 O<sub><span style="vertical-align:sub;">2</span></sub> (l) + H<sub><span style="vertical-align:sub;">2</span></sub>O + 2Fe<sup><span style="vertical-align:super;">+2</span></sup> → 2OH<sup><span style="vertical-align:super;">- </span></sup>+ 2Fe<sup><span style="vertical-align:super;">+3</span></sup></span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">再生部分總方程式</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">1/2 O<sub><span style="vertical-align:sub;">2</span></sub> (g) + H<sub><span style="vertical-align:sub;">2</span></sub>O + 2Fe<sup><span style="vertical-align:super;">+2</span></sup> → 2OH<sup><span style="vertical-align:super;">-</span></sup> + 2Fe<sup><span style="vertical-align:super;">+3</span></sup></span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">在水配比溶液中，亞鐵離子（Fe<sup><span style="vertical-align:super;">+2</span></sup>）和高鐵離子(Fe<sup><span style="vertical-align:super;">+3</span></sup>)都不能穩定存在，通常情況下容易經如下反應形成氫氧化鐵或硫化鐵沉淀：</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">Fe<sup><span style="vertical-align:super;">+3</span></sup> + 3OH<sup><span style="vertical-align:super;">-</span></sup> → Fe(OH)<sub><span style="vertical-align:sub;">3</span></sub>(s)</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">Fe<sup><span style="vertical-align:super;">+2</span></sup> + S<sup><span style="vertical-align:super;">-2</span></sup> → FeS (s)</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">為了阻止上述沉淀的產生，BLUER-PRO系統采用了一種獨特的螯合劑（XR-SR2），使得水配比液中的鐵能夠在寬泛的pH值范圍內保持穩定的離子狀態。螯合劑是一種有機化合物，它將金屬離子包裹在一個爪狀的結構中，使金屬離子與兩個或多個非金屬離子形成化學鍵。</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">酸氣的處理中伴隨著二氧化碳(CO<sub><span style="vertical-align:sub;">2</span></sub>)氣體，尤其是隨著分壓的提高，降低pH值的副反應會隨之發生。二氧化碳易溶于水，會形成重碳酸鹽(HCO<sub><span style="vertical-align:sub;">3</span></sub><sup><span style="vertical-align:super;">-</span></sup>)和碳酸鹽(CO<sub><span style="vertical-align:sub;">3</span></sub><sup><span style="vertical-align:super;">-2</span></sup>)，反應如下：</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">CO<sub><span style="vertical-align:sub;">2</span></sub> (g) + H<sub><span style="vertical-align:sub;">2</span></sub>O (l) ↔ H<sub><span style="vertical-align:sub;">2</span></sub>CO<sub><span style="vertical-align:sub;">3</span></sub> (l)</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">H<sub><span style="vertical-align:sub;">2</span></sub>CO<sub><span style="vertical-align:sub;">3</span></sub> (l) ↔ H<sup><span style="vertical-align:super;">+</span></sup> + HCO<sub><span style="vertical-align:sub;">3</span></sub><sup><span style="vertical-align:super;">- </span></sup> </span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">HCO<sub><span style="vertical-align:sub;">3</span></sub><sup><span style="vertical-align:super;">-</span></sup> ↔ CO<sub><span style="vertical-align:sub;">3</span></sub><sup><span style="vertical-align:super;">-2</span></sup> + H<sup><span style="vertical-align:super;">+</span></sup></span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">為了穩定配比溶液的pH值，需要在系統中加入如氫氧化鉀類的堿性物質，它與二氧化碳的反應入下：</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">CO<sub><span style="vertical-align:sub;">2</span></sub> (g) + H<sub><span style="vertical-align:sub;">2</span></sub>O(l) ↔ H<sub><span style="vertical-align:sub;">2</span></sub>CO<sub><span style="vertical-align:sub;">3</span></sub>(液體)</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">H<sub><span style="vertical-align:sub;">2</span></sub>CO<sub><span style="vertical-align:sub;">3</span></sub>(液體) + 2KOH ↔ K<sub><span style="vertical-align:sub;">2</span></sub>CO<sub><span style="vertical-align:sub;">3</span></sub> + 2H<sub><span style="vertical-align:sub;">2</span></sub>O</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">K<sub><span style="vertical-align:sub;">2</span></sub>CO<sub><span style="vertical-align:sub;">3</span></sub> + H<sub><span style="vertical-align:sub;">2</span></sub>CO<sub><span style="vertical-align:sub;">3</span></sub> ↔ 2KHCO<sub><span style="vertical-align:sub;">3</span></sub></span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">在加入KOH后，配比溶液中形成HCO<sub><span style="vertical-align:sub;">3</span></sub><sup><span style="vertical-align:super;">-</span></sup>——CO<sub><span style="vertical-align:sub;">3</span></sub><sup><span style="vertical-align:super;">-2</span></sup>緩沖平衡液，之后CO<sub><span style="vertical-align:sub;">2</span></sub>就不在被吸收了，也不再消耗堿，但為了抑制一些副反應和補充隨硫磺餅損失掉的鹽，還需要添加少量的堿。</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:16px;">由于水配比溶液中，硫磺以顆粒狀存在，所以必須通過類似沉淀的方法進行固液分離。一般來說，硫磺在吸收塔中形成，在加入表面活性劑（XR-SR6）后，硫磺顆粒在水配比溶液中被潤濕。由于硫磺密度是水密度的大約兩倍，所以沉淀速度相對較快。最后生成硫磺從系統沉降分離出來。</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size: 16px;">BLUER-PRO工藝可設計用于處理各種含硫化氫氣體。在許多工業應用領域中可實現99.99%以上的H2</span>S 去除率。這些領域涵蓋天然氣開采、石油提煉、生物氣處理、垃圾填埋沼氣處理、煉焦、地熱氣體發電、飲料業CO<span style="font-size: 13.3333px;">2</span><span style="font-size: 16px;">氣體生產、潤滑油生產等等。</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;"><span style="font-size:16px;">在這些工業生產中，需處理的氣體流量從幾個立方米到上</span>萬立方米（工況下流量），每天產生的硫從0.2</span><span style="font-size:12.0000pt;">-</span><span style="font-size:12.0000pt;">25噸</span><span style="font-size:12.0000pt;">/</span><span style="font-size:12.0000pt;">天。系統處理的含硫氣體量從</span><span style="font-size:12.0000pt;">100ppmv </span><span style="font-size:12.0000pt;">的</span><span style="font-size:12.0000pt;">H</span><sub><span style="vertical-align:sub;"><span style="font-size:12.0000pt;">2</span></span></sub><span style="font-size:12.0000pt;">S </span><span style="font-size:12.0000pt;">到</span><span style="font-size:12.0000pt;">100%</span><span style="font-size:12.0000pt;">的</span><span style="font-size:12.0000pt;">H</span><sub><span style="vertical-align:sub;"><span style="font-size:12.0000pt;">2</span></span></sub><span style="font-size:12.0000pt;">S</span><span style="font-size:12.0000pt;">。</span></span></p> <h2><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">3.2 工藝特點</span></span></h2> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">BLUER-PRO工藝具有傳統液相氧化催化法的所有優點，具體如下：</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">（1）硫化氫脫除率高，一步反應的脫除率達到</span><span style="font-size:12.0000pt;">99.99%</span><span style="font-size:12.0000pt;">以上，處理過的尾氣</span><span style="font-size:12.0000pt;">H</span><sub><span style="vertical-align:sub;"><span style="font-size:12.0000pt;">2</span></span></sub><span style="font-size:12.0000pt;">S</span><span style="font-size:12.0000pt;">濃度在可以在5</span><span style="font-size:12.0000pt;">ppm</span><span style="font-size:12.0000pt;">以下。</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">（2）應用范圍廣，可以處理各種含</span><span style="font-size:12.0000pt;">H</span><sub><span style="vertical-align:sub;"><span style="font-size:12.0000pt;">2</span></span></sub><span style="font-size:12.0000pt;">S</span><span style="font-size:12.0000pt;">氣體，選擇性高?！　?/span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">（</span><span style="font-size:12.0000pt;">3</span><span style="font-size:12.0000pt;">）操作彈性大，能夠適應原料氣中</span><span style="font-size:12.0000pt;">H</span><sub><span style="vertical-align:sub;"><span style="font-size:12.0000pt;">2</span></span></sub><span style="font-size:12.0000pt;">S</span><span style="font-size:12.0000pt;">濃度、原料氣流量從</span><span style="font-size:12.0000pt;">0-100%</span><span style="font-size:12.0000pt;">的大幅度波動變化?！　?/span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">（</span><span style="font-size:12.0000pt;">4</span><span style="font-size:12.0000pt;">）環境友好，沒有三廢產生?！　?/span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">（</span><span style="font-size:12.0000pt;">5</span><span style="font-size:12.0000pt;">）反應條件溫和，為液相、常溫常壓反應過程?！?/span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">（</span><span style="font-size:12.0000pt;">6</span><span style="font-size:12.0000pt;">）工藝簡單，開、停工及日常操作均簡單?！?/span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">（</span><span style="font-size:12.0000pt;">7</span><span style="font-size:12.0000pt;">）經濟性能高，占地面積小，投資費用少，日常運行成本低?！　?/span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">（</span><span style="font-size:12.0000pt;">8</span><span style="font-size:12.0000pt;">）安全性能高，系統不使用任何有毒的化學物質，硫磺產品中沒有</span><span style="font-size:12.0000pt;">H</span><sub><span style="vertical-align:sub;"><span style="font-size:12.0000pt;">2</span></span></sub><span style="font-size:12.0000pt;">S</span><span style="font-size:12.0000pt;">氣體?！　?/span></span></p> <p style="text-indent:24.0000pt;"><span style="font-family:arial,helvetica,sans-serif;"><span style="font-size:12.0000pt;">（</span><span style="font-size:12.0000pt;">9</span></span><span style="font-size:12.0000pt;"><span style="font-family:仿宋;"><span style="font-family:arial,helvetica,sans-serif;">）運行可靠，獨特的設計能夠保證無堵塞現象發生，保</span>證長周期穩定運行。</span></span></p> <p style="text-indent:24.0000pt;"><span style="font-size:12.0000pt;"><span style="font-family:仿宋;">（</span>10）硫磺品質好，雜質少。</span></p> </div> </div> </article> </div> <div class="js_infoDetail_content item_hide"></div>   <div class="e_box e_box-000 p_assist"> <div class="e_box e_box-000 p_KeywordBox "> <div class="e_title e_name-001 p_nameA "> <div class="font"><i class="iconfont"></i> <span class="i_KeywordBox">關鍵詞：</span></div> </div> <div class="e_box e_box-000 p_keywords">  <a class="e_link e_link-000 p_LinkB"> <div class="e_title e_MajorLink-001 p_tag"> <div class="font"><i class="iconfont"></i>濕法螯合鐵工藝</div> </div> </a> </div> </div>  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